Silicone DC-868LV

Silicone DC-868LV
1. PRODUCT AND COMPANY IDENTIFICATION

Product name:
Silicone DC-868LV
Chemical name:

Application: Silicone surfactant, Silicone oil, Polyalkyleneoxidemethylsiloxane copolymer

Used for polyurethane foam

Supplier:

Shanghai DAOKOW PU Material CO. ,LTD
1#,NO. 628 ,Zhudai Road ,Zhuqiao industrial park
Jiading district , Shanghai, China （201815）

Contact numbers:
Emergency Response (24 hours): (86)-21-59963900

Fax:(86)-21-59963955
2. COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENT CAS# CONCENTRATION
Silicone Polyalkyleneoxide Copolymer 64365-23-7 50.0-60.0 %
Polyalkylene glycol
110-98-5
40.0-50.0%

Note(s): See Section 15 for chemicals appearing on Federal or State Right-To-Know lists.

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
WARNING!

CAUSES EYE IRRITATION.

4. FIRST AID MEASURES

Swallowing
Give water to drink.Obtain medical attention.

Skin
Remove contaminated clothing.Wash skin with soap and water.Obtain medical attention if discomfort persists.

Inhalation
Remove to fresh air.Obtain medical attention.

Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes.Obtain medical attention immediately.

Notes to physician
Toxicology studies have shown this material to be of very low acute toxicity. There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient.

5. FIRE-FIGHTING MEASURES

Flash point: >93 °C

Flammable limits
Lower limit: Not available
Upper limit: Not available

Special fire fighting procedures
Do not direct a solid stream of water or foam into hot, burning pools: this may cause frothing and increase fire intensity.

Special protective equipment for firefighters
Self-contained breathing apparatus. Body covering protective clothing.

Extinguishing media
Suitable: Large fires:
– alcohol-type foam or universal-type foams
Small fires:
– CO2
– dry chemical

Unsuitable: None.

Unusual fire and explosion hazards
None known.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Avoid contact with eyes and skin.Avoid contact with liquid and vapors.Wear suitable protective equipment.

Environmental precautions
Prevent runoff.

Methods for cleaning up
Cover with absorbent or contain.
Collect for disposal.
Observe government regulations.

7. HANDLING AND STORAGE

HANDLING
Handling precautions
Do not swallow. Do not get in eyes, on skin, on clothing. Avoid breathing vapor, aerosol and mist. Use with adequate ventilation. Wash thoroughly after handling.

STORAGE
Storage requirements
Keep away from heat and flame. Keep container closed.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

PERSONAL PROTECTION
Respiratory protection
Self-contained breathing apparatus in high vapor concentrations.

Hand protection / protective gloves
Recommended order of use:
4H
Butyl
Neoprene
Nitrile (NBR)
PVC-coated

Eye protection
Monogoggles

Skin protection
Chemical protective clothing.

Other protective equipment
Eye bath
Safety shower

ENGINEERING CONTROLS
Ventilation
General mechanical room ventilation is satisfactory for normal handling and storage operations.
Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air.

EXPOSURE LIMITS
No exposure limits have been established
9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Physical state

Liquid
Color

Straw transparent amber
Odor

Polyether

OTHER PROPERTIES
Boiling point

> 150 °C at STP unless specified below.
Copolymer

Melting point

< 0 °C at STP unless specified below.

pH

Not available

Specific gravity (H2O=1)

1.0300at 25 °C ( 1,013 hPa)

Vapor pressure
< 1.33 hPa (1.00 mmHg) at 20 °C

Vapor density (air=1)

Heavier than air

Solubility in water

Soluble

Evaporation rate (Butyl Acetate=1)

< 1

Flash point

>93°C
Method:Pensky-Martens closed cup ASTM D 93

Upper explosion limits

Not available

Lower explosion limits

Not available

Percent volatiles

Not determined

Molecular weight

Copolymer

10. STABILITY AND REACTIVITY

Stability: Stable.

Stability – Conditions to avoid
None known.

Incompatible materials
None currently known.

Hazardous combustion products
Burning can produce the following combustion products:
Oxides of carbon.
Oxides of silicon.
Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant.
Acute overexposure to the products of combustion may result in irritation of the respiratory tract.

Hazardous polymerization: Will not occur.

Hazardous polymerization – Conditions to avoid
None known.

11. TOXICOLOGICAL INFORMATION

SWALLOWING
Acute effects
No evidence of harmful effects from available information.

SKIN ABSORPTION
Acute effects
No evidence of harmful effects from available information.

INHALATION
Acute effects
Short-term harmful health effects are not expected from vapor generated at ambient temperature.

SKIN CONTACT
Acute effects
No evidence of harmful effects from available information.

EYE CONTACT
Acute effects
Causes irritation.
Causes the following effects:
– stinging
– discomfort
– pain
May cause the following effects:
– excess redness of the conjunctivae
– swelling of the conjunctivae

Medical conditions aggravated by overexposure
A knowledge of the available toxicology information and of the physical and chemical properties of the material suggests that overexposure is unlikely to aggravate existing medical conditions.

Other effects of overexposure
No adverse effects anticipated from available information.

SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH
The following information is based on analogy with a similar material:
This material was negative in a Salmonella Typhimurium/ Escherichia coli mutagenicity assay.

12. ECOLOGICAL INFORMATION

All available ecological data have been taken into account for the development of the hazard and precautionary information contained in this Safety Data Sheet.
13. DISPOSAL CONSIDERATIONS

General:
Incinerate in a furnace where permitted under appropriate Federal, State, and local regulations.

14. TRANSPORT INFORMATION
DOT Classification
This product is not regulated by DOT. Freight description road: OIL, O/T PETROLEUM, LUBRICATING, NOIBN

IMDG Classification
This product is not regulated by IMDG.

ICAO Classification
This product is not regulated by ICAO.

15. REGULATORY INFORMATION
Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification of the National Response Center of release of quantities of hazardous substances equal to or greater than the reportable quantities (RQ’s) in 40CFR302.4.
Components present in this product at a level which could require reporting under the statute are:
**** NONE ****

Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQ’s) and release reporting based on Reportable Quantities (RQ’s) in 40CFR355 (used for SARA 302 and 304).
Components present in this product at a level which could require reporting under the statute are:
**** NONE ****

Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40CFR372 (for SARA 313). This information must be included in MSDS’s that are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
**** NONE ****

Massachusetts Right-To-Know Substance List (MSL)–Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
**** NONE ****

Pennsylvania Right-To-Know Hazardous Substance List–Hazardous Substances and Special Hazardous Substances on the list must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
**** NONE ****

EPA Hazard Categories (SARA 311, 312): Immediate Health Hazard

California Proposition 65
**** NONE ****

California SCAQMD Rule 443.1 VOC’s
Volatile Organic Components (VOC’s) = Substances with vapor pressure of => 0.5 mmHg at 104’C (219.2’F).
****NOT DETERMINED****

CHEMICAL INVENTORY
Canada: The ingredients of this product are on the DSL.

Europe: The ingredients of this product are on the EINECS inventory.

United States: The ingredients of this product are listed on the TSCA inventory or are exempt.

Australia: This product, or the components, is listed or exempt from listing on the Australian Inventory of Chemical Substances (AICS).

Japan: This product, or the components, is listed or exempt from listing on the Existing and New Chemical Substances (ENCS) list.

Korea: This product is listed on the Existing Chemicals List (ECL).

Philippines: This product, or the components, is listed or exempt from listing on the Philippines Inventory of Chemicals and Chemical Substances (PICCS).

16. OTHER INFORMATION

RECOMMENDED USES AND RESTRICTIONS
Please consult the product and/or application information bulletins for this product.

HMIS RATING
Health: 1 Flammability: 1 Reactivity: 0 PPI: X

LEGEND

STP Standard temperature and pressure
W/W Weight/Weight
0 (HMIS) Minimal hazard
1 (HMIS) Slight hazard
2 (HMIS) Moderate hazard
3 (HMIS) Serious hazard
4 (HMIS) Severe hazard
X (HMIS) Personal protection rating to be supplied by user depending on use conditions

The opinions expressed herein are those of qualified experts within Shanghai DAOKOW PU Material CO. ,LTD. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and of these opinions and the conditions of use of this product are not within the control of Shanghai DAOKOW PU Material CO. ,LTD., it is the user’s obligation to determine the conditions of safe use of the products.